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Or, brew a beer with RO and add the salts to the glass afterwards. This could be a glorious exercise, drinking beer after beer with various levels of salts to see just when we can "perceive" the dryness imparted by our gypsum additions! I would likely fall over first, but all in the name of progress.
Ok, would a taste test like this actually work or do the additives need to be in the mash and boil?
A test like this would definitely work. Add table salt to a beer and see what happens. It's a great experiment.
Why do we add salts to the mash or the boil? For convenience or do they actually "affect the beer". If your pH is in line - and that can be achieved much easier with your favorite acid and not various additions of salts - what else does the mash really need? I understand a bit of Calcium is good for yeast health, but typical malt provides that.
Now I'm not suggesting mashing with distilled water, but for practical purposes, wouldn't we get a better idea of what the salts are doing to our beer if we just added them to the glass? Again, if we make a beer with "Insert Water Profile Here", how do we know that we wouldn't have preferred it with twice the SO4 or half the Na? We take these water profiles on faith. A good food recipe almost always ends with "salt and pepper to taste".
Now...once we know what we like, then sure, add the salts to the mash because it really is convenient.