very low pH of strike water from calculator

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I am new to Brewers Friend and relatively new to all grain brewing. I am brewing a kit from Label Peelers. Simple grain bill with 12.5# pale malt. The recipe is here: https://www.brewersfriend.com/mash-chemistry-and-brewing-water-calculator/?id=X7JHWHW There will be some additions of pineapple juice concentrate in the fermenter at stages, but not in the mash or boil, so not of consequence for my question. My question is on the pH of my strike water before mashing in. I am using city water and entered the data from their brewer's info page that is updated frequently and tends to be consistent - see below. Water is alkaline and they raise the pH to 8.6. I verified that coming out of the tap with a calibrated pH meter.
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When I add my desired salts (see below) and enough phosphoric acid (50ml of 10% concentration) to get the predicted mash pH to ~5.3, the pH of my strike water before mashing in is 3.1. I mixed up a bucket to test this and verified that it was 3.1 pH after mixing and then again after 12 hours, checked with a calibrated pH meter. It requires ~35 ml of acid to get my sparge water to pH 5.4. I decided not to brew until I asked some other folks for their experience. It seems odd that my water for mashing would be that much lower in pH when my mash target is 5.3 pH and the grain should lower pH in the mashing process. I understand that there is significant buffering potential in the grain, but this seems out of whack to me that 3.1 + grain = 5.3. I would appreciate any expert and experienced insight that anyone could provide.
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Others will also comment.

50 ml is a lot of acid. The pH of your water is irrelevant, since its buffering power (ability to resist pH changes) is minuscule. Certainly small enough to be ignored. That's why 3.1 + grain = 5.4. I bet that 6.8 + grain = 5.5, really.

What matters is mash pH, and that is primarily a function of your malted grain (or dme or lme), with some impact from the brewing salts.

I hesitate to advise you to ignore the pH estimate, but 50 ml of 10% for a 5-gallon batch is a lot of acid. I recommend cutting that back a lot, maybe to 10 ml max.

12.5 pounds of pale 2-row should not need acid at all in my experience, but definitely wait a short time for others to chime in.
 
If your city water is truely that high of PH, consider an alternate water source. 50ml of acid might be reasonable to try to lower it 3 full pts. I would put it in 10ml steps though. just to make sure. if you go too far the other way, it wont convert very well.
 
Lots of CA products, that is where the high ph comes from
 
I'd be very reluctant to brew with that water.
Also, what's the taste threshold for that acid? I use Lactic and although the taste threshold is supposed to be ~10ml in 5 gallons, I don't like it when it's over 5ml/5gal.
 
My alkalinity is 205 and I've opted to get an RO filter for this same reason.
 
Thanks to each of you for your input. I treated my water with 25ml of 10% phosphoric acid before mash in and then tested 10 minutes after mash in and added 10ml more to get to my mash target of 5.3 pH. Sparge water got 25ml. Per the question, phosphoric acid is relatively flavor neutral (https://www.homebrewtalk.com/threads/why-phosphoric-acid-is-flavor-neutral.601471/), which is why I use it. Used extensively in soft drinks and food products. I have brewed quite good beer from this water before, at least to my non-expert palate. Hopefully, I can report after the batch finishes. I have access to another soft water source and will try brewing from that, maybe my next batch.
 

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