I'm playing around with water chemistry here http://www.brewersfriend.com/mash-chemistry-and-brewing-water-calculator/?id=X4XQ14X, and I noticed that changing water volumes (mash and total) have no effect on mash pH. Considering that I've got this set up for distilled water, I would think that increasing the water volume to say, 100 gallons, would raise the pH somewhat. Other calculators, such as Bru'n water *do* show an increase in pH when increasing water volume. It's very likely that I'm misunderstanding something here, because math. But I'd appreciate any info or explanation. Thanks.