Heat, especially moist heat, can effectively inactivate most microorganisms and can do so relatively rapidly. A temperature of 175 degrees F (80 degrees C) for 5-10 min, for example, will destroy all active bacteria, yeast, and fungi.
For most home brewing purposes, boiling in water for 20-60 min (approximately 212 degrees F [100 degrees C]) is sufficient to sterilize liquids such as wort for brewing and starters and solutions of priming sugar.
Boiling water can also be used in place of bleach to sterilize bottle caps, stainless steel kegs, and other utensils. It is also an effective way to remove residual bleach or other sanitizing agents from brewing equipment.
Put as many caps as you will need into a pot and cover them with water. Bring this mixture to a boil for one minute - not longer - and then turn off the heat and put the pot on a cold burner. Cover the pot with a lid and let the caps sit, submerged, for ten to fifteen minutes in the hot water. This
pasteurizes the caps. Remember: if you boil caps too hard, too long, you can peel the rubber liners out of the inside of the caps.
Do not boil for more than a minute, but the caps DO need to sit in the hot water for at least ten minutes....
http://www.beertools.com/html/tutorial/ ... step01.php
you can find this on the page of the above website
Caps
Unused bottle caps are pressed onto bottles with a bottle capper to seal and maintain pressure. They are sanitized by boiling.
Although none of the info above says it will make them seal better, I'm sure it does. Softer liners will compress better allowing for a better seal.