i have the spunding valve set to 5psi. roughly 4.5 gallons has been added. thanks for the good info and helpFermenting in a keg: you must leave head space for the foam (Krausen). It could get into the spunding valve and clog it, somewhat dangerous as pressure will build.
The keg can handle something like 100 psi, and at that pressure, the yeast will have stopped working, so it is self limiting to a point.
I would not put in more than 4 gallons.